Water pH and pOH Equations:
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pH and pOH are logarithmic measures of the acidity and basicity of aqueous solutions. pH represents the negative logarithm of hydrogen ion concentration, while pOH represents the negative logarithm of hydroxide ion concentration. For pure water at 25°C, both pH and pOH equal 7.
The calculator uses the fundamental water dissociation equations:
Where:
Explanation: These equations are interconnected - knowing any one value allows calculation of all others through the relationship pH + pOH = 14.
Details: Accurate pH and pOH calculations are essential in chemistry, biology, environmental science, and industrial processes. They help determine solution acidity/basicity, predict chemical behavior, and maintain optimal conditions in various applications.
Tips: Enter any one known value (H+ concentration, OH- concentration, pH, or pOH) and the calculator will compute the remaining values. All concentrations should be in mol/L, while pH and pOH are unitless.
Q1: What is the relationship between pH and pOH?
A: pH + pOH = 14 for aqueous solutions at 25°C. This relationship comes from the water dissociation constant Kw = 10⁻¹⁴.
Q2: What are normal pH values for water?
A: Pure water has pH = 7 (neutral). Natural waters typically range from pH 6.5-8.5. Values below 7 are acidic, above 7 are basic.
Q3: How does temperature affect pH calculations?
A: Kw changes with temperature, so the pH + pOH relationship varies. At higher temperatures, neutral pH is less than 7.
Q4: Can this calculator handle very concentrated solutions?
A: For highly concentrated solutions, activity coefficients should be considered for accurate results.
Q5: What is the significance of the 10⁻¹⁴ value?
A: This is the water dissociation constant at 25°C, representing the product of [H⁺] and [OH⁻] in any aqueous solution.